ECEC Mechanism Simulator

Simulate an ECEC reaction pathway.

Simulation Parameters

Initial Potential (E_start) [V]

Switching Potential (E_vertex) [V]

Scan Rate [V/s]

Area [cm²]

Temperature [°C]

$$ \text{O} + n_1\text{e}^- \rightleftharpoons \text{R} $$

$$ \text{R} \mathrel{\underset{k_{b1}}{\overset{k_{f1}}{\rightleftharpoons}}} \text{X} $$

$$ \text{X} + n_2\text{e}^- \rightleftharpoons \text{Y} $$

$$ \text{Y} \mathrel{\underset{k_{b2}}{\overset{k_{f2}}{\rightleftharpoons}}} \text{Z} $$

Formal Potential (E⁰'₁) [V]

Std. Rate Constant (k⁰₁) [cm/s]

Transfer Coeff. (α₁)

Electrons Transferred (n₁)

Forward Rate (k_f1) [s⁻¹]

Backward Rate (k_b1) [s⁻¹]

Formal Potential (E⁰'₂) [V]

Std. Rate Constant (k⁰₂) [cm/s]

Transfer Coeff. (α₂)

Electrons Transferred (n₂)

Forward Rate (k_f2) [s⁻¹]

Backward Rate (k_b2) [s⁻¹]

Conc. (C_O) [mM]

Conc. (C_R) [mM]

Diff. Coeff. (D_O) [10⁻⁶ cm²/s]

Diff. Coeff. (D_R) [10⁻⁶ cm²/s]

Diff. Coeff. (D_X) [10⁻⁶ cm²/s]

Diff. Coeff. (D_Y) [10⁻⁶ cm²/s]

Diff. Coeff. (D_Z) [10⁻⁶ cm²/s]

Click "Run Simulation" to see your cyclic voltammogram.